Safe Work Australia
Workplace exposure standards for airborne contaminants (2024)
Employers must assess the risks for each identified hazard. When assessing the risk, the degree and likelihood of employees or other people being exposed to the hazards must be considered.
The presence of unsafe levels of methyl bromide (MeBr) is a hazard to the health and safety of persons involved in unpacking shipping containers.
Shipping containers that have been fumigated and ventilated by fumigators may still contain a significant quantity of methyl bromide (MeBr) due to poor venting procedures, desorption or entrapment of the gas in the packaging and materials used to secure the container cargo (dunnage). This may present a risk to persons involved in unpacking these containers.
MeBr affects the central nervous system.
Depending on the level of exposure, breathing in MeBr may cause:
Employers must ensure that employees are not exposed to levels of MeBr above the current Workplace exposure standards for airborne contaminants (2024). Current limits are 5 ppm (parts per million).
Workplace exposure standards for airborne contaminants (2024)
Where there is a risk to health and safety, employers must, so far as is reasonably practicable, eliminate the risk. If it is not reasonably practicable to eliminate the risk, the risk must be reduced, so far as is reasonably practicable.
Employers must eliminate or reduce, as far as is reasonably practicable, the exposure to MeBr by employees or contractors who unpack shipping containers.
Use the hierarchy of control to identify and put in place the highest order of control. In many cases several control measures may need to be used to reduce the risk, so far as reasonably practicable.
The following control measures should be used when controlling exposure to unsafe levels of MeBr:
If in doubt, treat the shipping container and everything inside as fumigated.

Fans or mechanical ventilation is recommended if there is:
If mechanical ventilation is not practicable or available, vent the container using natural ventilation. General fumigation procedures recommends 12 hours. Refer to AS 2476-2008: General fumigation procedures.
General fumigation procedures
Following ventilation, before entry, test the air inside the container using suitable air testing equipment to ensure that the MeBr level is below 5 ppm.
If the container is tightly packed, partially unpack the container wearing appropriate PPE and allow further venting for a short period. Repeat this process until unpacking is complete.
If shipping containers are regularly handled, a range of equipment is available to test for MeBr — consider using this equipment.
The detection sensitivity of air testing equipment can vary, as shown in the following table.
| Equipment | Level detected |
|---|---|
Halide leak detection lamp | Reliably above 30 ppm (Lamp colour changes may be observed at lower concentrations) |
Gas detector tube | less than 5ppm |
Electronic instrument | less than 5ppm |
A halide leak detection lamp is simple to use and does not need calibration.
A halide leak detection lamp works on the principle that a flame in contact with a clean piece of copper will burn with a green to blue flame if vapour of an organic halide is present in the surrounding air. They cannot be relied upon for accurate quantitative measurements.
Halide leak detection lamps are useful for indicating the presence of immediately dangerous concentrations, for preliminary checking the effectiveness of aeration.
A Halide leak detection lamp or any electrical equipment not intrinsically safe must not be used where flammable goods are present.
Intrinsic safety is a protection technique for safe operation of electrical equipment in hazardous areas. The technique limits the energy, electrical and thermal, available for ignition — preventing sparks and keeping temperatures low, which can help to prevent explosion in a flammable atmosphere.
Employers must provide any necessary information, instruction, training or supervision to relevant employees so that they can do their work in a way that is safe and without risks to health.
Provide information, instruction, training, or supervision about how employees can unpack shipping containers safely.
This information includes:
Employers have duties under the Occupational Health and Safety Act and Regulations.
Occupational health and safety – your legal duties provides an overview of employer and employee responsibilities under the Occupational Health and Safety Act 2004.
Employers must also, so far as is reasonably practicable, consult with employees, contractors, labour hire workers and any health and safety representatives (HSRs) about health and safety matters.
This includes consulting when:
You must give your employees and any HSRs information about health and safety matters that affect them or are likely to affect them. Give them enough time to consider, discuss and then give their feedback.
If it is reasonably practicable, you must provide the information to any HSRs a reasonable time before it is provided to employees.
Information should be in a form that employees and HSRs can easily understand. They may need information such as technical guidance about workplace hazards and risks. For example, information about equipment and substances. They may also need information about how work is organised. For example, systems, reports, procedures and guidance material.
Prostate cancer and toxicity from critical use exemptions of methyl bromide